Although aluminum is the most abundant metal in the earth's crust, it is never found free in nature. All of the earth's aluminum has combined with other elements to form compounds. Two of the most common compounds are alum, such as potassium aluminum sulfate (KAl(SO₄)₂ˇ¤12H₂O), and aluminum oxide (Al₂O₃). About 8.2% of the earth's crust is composed of aluminum.

Scientists suspected than an unknown metal existed in alum as early as 1787, but they did not have a way to extract it until 1825. Hans Christian Oersted, a Danish chemist, was the first to produce tiny amounts of aluminum. Two years later, Friedrich Wöhler, a German chemist, developed a different way to obtain aluminum. By 1845, he was able to produce samples large enough to determine some of aluminum's basic properties. Wöhler's method was improved in 1854 by Henri Étienne Sainte-Claire Deville, a French chemist. Deville's process allowed for the commercial production of aluminum. As a result, the price of aluminum dropped from around $1200 per kilogram in 1852 to around $40 per kilogram in 1859. Unfortunately, aluminum remained too expensive to be widely used.

Two important developments in the 1880s greatly increased the availability of aluminum. The first was the invention of a new process for obtaining aluminum from aluminum oxide. Charles Martin Hall, an American chemist, and Paul L. T. H¨¦roult, a French chemist, each invented this process independently in 1886. The second was the invention of a new process that could cheaply obtain aluminum oxide from bauxite. Bauxite is an ore that contains a large amount of aluminum hydroxide (Al₂O₃ˇ¤3H₂O), along with other compounds. Karl Joseph Bayer, an Austrian chemist, developed this process in 1888. The Hall-H¨¦roult and Bayer processes are still used today to produce nearly all of the world's aluminum.